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These data were collected by AÃ­da F. RÃ­os of Institute of Marine Research Vigo (IIM) as part of the Biomass-IV and Biomass-IV Expedition ANA Cruise dataset. CDIAC associated the following cruise ID(s) with this dataset: 67SL19881117 and Biomass-IV Expedition ANA Cruise</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Total alkalinity;
Abbreviation: TA;
Observation type: discrete;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Measured;
Type of titration: automatic;
Uncertainty: The precision was 2 Î¼mol/kg-1 (0.1%) for alkalinity and 0.005 for pH. In order to correct the drift and bias during the cruise due to slight changes in the reference electrodes, routine and daily measurements of both variables for big container (25l.) were made.;
Method reference: Takahashi, T., Olafsson, J., Goddard, J.G., Chipman, D.W. and Sutherland, S.C., 1993. Seasonal variation of CO2 and nutrients in the High-Latitude Surface Oceans: A comparative Study. Global Biogeochemical Cycles, 7(4), 843-878. Mehrbach, C., Culberson, C.H., Hawley, J.E. and Pytkowicz, R.M., 1973. Measurements of the apparent dissociation constants of carbonic in seawater at atmospheric pressure. Limnol. Oceanogr., 18: 897-907. Millero, F.J., 1995. Thermodynamics of the carbon dioxide system in the oceans. Geochim. et Cosmochim. Acta, 59 (4): 661-677. Millero, F.J., Byrne, R.H., Wanninkhof, R., Freely, R., Clayton, T., Murphy, P. and Lamb, M.F., 1994. The internal consistency of CO2 measurements in the equatorial Pacific. Mar. Chem., 44: 269-280. RÃ­os, A.F. and RosÃÂ³n, G., 1996. Surface pCO2. In: Le Groupe CITHER 2 (Editors), Campagne CITHER-2. Recueil de donnÃ©es. Volume 3: Traceurs GÃ©ochimiques. Brest, 967 pp. Roy, R.N., Roy, L.N., Vogel, K.M., Porter-Moore, C., Pearson, T., Good, C.E., Millero, F.J. and Campbell, D.M., 1993. The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45Â°C. Mar. Chem., 44: 249-267. Lee, K. and Millero, F.J., 1995. Thermodynamics studies of carbonate system in seawater. Deep-Sea Res., 42 (11/12): 2035-2061. PÃ©rez, F.F. and Fraga, F., 1987a. The pH measurements in seawater on NBS scale. Mar. Chem., 21: 315-327. PÃ©rez, F.F. and Fraga, F., 1987b. A precise and rapid analytical procedure for alkalinity determination. Mar. Chem., 21: 169-182. Weiss, R.F., 1974. Carbon dioxide in water and seawater: the solubility of a non-ideal gas. Mar. Chem., 2: 203-215.</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: pH;
Abbreviation: pH;
Observation type: discrete;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Measured;
Detailed sampling and analyzing information: A Ross Orion 81-04 electrode calibrated with 7.413 NBS buffer, was used to determine pH. The temperature was also measured by means of a Pt-100 probe. pH values were normalised to 15Â°C to avoid the temperature effect over pH (PÃ©rez and Fraga, 1987a). Automatic titration was used to measure alkalinity to final pH 4.44 with HCl (PÃ©rez and Fraga, 1987b).;
Uncertainty: The precision was 2 Î¼mol/kg-1 (0.1%) for alkalinity and 0.005 for pH. In order to correct the drift and bias during the cruise due to slight changes in the reference electrodes, routine and daily measurements of both variables for big container (25l.) were made.</gco:CharacterString>
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Abbreviation: SALNIY;
Controlled vocabulary name: SALINITY;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
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Abbreviation: CTDTMP;
Unit: DEG_C;
Controlled vocabulary name: WATER TEMPERATURE;
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Controlled vocabulary name: DISSOLVED OXYGEN;
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                <gco:CharacterString>Parameter or Variable: NITRAT;
Abbreviation: NITRAT;
Unit: UMOL/KG;
Controlled vocabulary name: NITRATE;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
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Abbreviation: SILCAT;
Unit: UMOL/KG;
Controlled vocabulary name: silicate;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
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Abbreviation: PH;
Controlled vocabulary name: pH;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: TALK;
Abbreviation: TALK;
Unit: UMOL/KG;
Controlled vocabulary name: total alkalinity;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
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            <gco:CharacterString>any type of water bottle sampling device

Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.</gco:CharacterString>
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            <gco:CharacterString>generic meter used to measure pH

Any of a class of instruments used to quantify pH in a water or other type of sample.</gco:CharacterString>
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