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            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/8" xlink:actuate="onRequest">CTD</gmx:Anchor>
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            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/50" xlink:actuate="onRequest">pH sensor</gmx:Anchor>
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            <gco:CharacterString>Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.</gco:CharacterString>
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            <gmd:MD_RestrictionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_RestrictionCode" codeListValue="otherRestrictions">otherRestrictions</gmd:MD_RestrictionCode>
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            <gco:CharacterString>Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.</gco:CharacterString>
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      <gmd:resourceConstraints xlink:title="Data License Statement">
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          <gmd:useConstraints>
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            <gmx:Anchor xlink:href="https://creativecommons.org/publicdomain/zero/1.0/" xlink:actuate="onRequest" xlink:title="CC0-1.0">This dataset has been dedicated to the public domain under a Creative Commons CC0 1.0 Universal (CC0 1.0) Public Domain Dedication.</gmx:Anchor>
          </gmd:otherConstraints>
          <gmd:otherConstraints>
            <gmx:Anchor xlink:href="https://spdx.org/licenses/CC0-1.0" xlink:actuate="onRequest" xlink:title="CC0-1.0">SPDX License: Creative Commons Zero v1.0 Universal (CC0-1.0)</gmx:Anchor>
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                    <gco:CharacterString>Web browser</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for data access and direct download.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0237/0306334/</gmd:URL>
                  </gmd:linkage>
                  <gmd:protocol>
                    <gco:CharacterString>FTP</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Any FTP client</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>FTP</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
            </gmd:MD_DigitalTransferOptions>
          </gmd:distributorTransferOptions>
        </gmd:MD_Distributor>
      </gmd:distributor>
    </gmd:MD_Distribution>
  </gmd:distributionInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="dataset">dataset</gmd:MD_ScopeCode>
          </gmd:level>
        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>NCEI Accession 0306334 v1.1 was published.</gco:CharacterString>
              </gmd:description>
              <gmd:dateTime>
                <gco:DateTime>2025-07-21T20:38:57Z</gco:DateTime>
              </gmd:dateTime>
              <gmi:output>
                <gmi:LE_Source>
                  <gmd:sourceCitation>
                    <gmd:CI_Citation>
                      <gmd:title>
                        <gco:CharacterString>NCEI Accession 0306334 v1.1</gco:CharacterString>
                      </gmd:title>
                      <gmd:date>
                        <gmd:CI_Date>
                          <gmd:date gco:nilReason="inapplicable" />
                          <gmd:dateType>
                            <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="publication">publication</gmd:CI_DateTypeCode>
                          </gmd:dateType>
                        </gmd:CI_Date>
                      </gmd:date>
                      <gmd:citedResponsibleParty>
                        <gmd:CI_ResponsibleParty>
                          <gmd:individualName gco:nilReason="inapplicable" />
                          <gmd:contactInfo>
                            <gmd:CI_Contact>
                              <gmd:onlineResource>
                                <gmd:CI_OnlineResource>
                                  <gmd:linkage>
                                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/0306334/1.1</gmd:URL>
                                  </gmd:linkage>
                                  <gmd:protocol>
                                    <gco:CharacterString>HTTPS</gco:CharacterString>
                                  </gmd:protocol>
                                  <gmd:name>
                                    <gco:CharacterString>NCEI Accession 0306334 v1.1</gco:CharacterString>
                                  </gmd:name>
                                  <gmd:description>
                                    <gco:CharacterString>published 2025-07-21T20:38:57Z</gco:CharacterString>
                                  </gmd:description>
                                  <gmd:function>
                                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
                                  </gmd:function>
                                </gmd:CI_OnlineResource>
                              </gmd:onlineResource>
                            </gmd:CI_Contact>
                          </gmd:contactInfo>
                          <gmd:role gco:nilReason="inapplicable" />
                        </gmd:CI_ResponsibleParty>
                      </gmd:citedResponsibleParty>
                    </gmd:CI_Citation>
                  </gmd:sourceCitation>
                </gmi:LE_Source>
              </gmi:output>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="dataset">dataset</gmd:MD_ScopeCode>
          </gmd:level>
        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Time;
Abbreviation: time;
Unit: seconds since 1970-01-01;
Observation type: Glider profile trajectory;
Measured or calculated: Measured;
Calculation method and parameters: Alias for m_present_time;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Profile center time;
Abbreviation: profile_time;
Unit: seconds since 1970-01-01;
Observation type: Glider profile trajectory;
Measured or calculated: Calculated;
Calculation method and parameters: Calculated timestamp corresponding to the mid-point of the profile;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Profile center longitude;
Abbreviation: profile_lon;
Unit: degrees_east;
Observation type: Glider profile trajectory;
Measured or calculated: CALCULATED;
Calculation method and parameters: Interpolated to provide an estimate of the longitude at the mid-point of the profile;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Profile center latitude;
Abbreviation: profile_lat;
Unit: degrees_north;
Observation type: Glider profile trajectory;
Measured or calculated: CALCULATED;
Calculation method and parameters: Interpolated to provide an estimate of the latitude at the mid-point of the profile;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Profile ID;
Abbreviation: profile_id;
Unit: 1;
Observation type: Glider profile trajectory;
Measured or calculated: CALCULATED;
Calculation method and parameters: Unique identifier of the profile. The profile ID is the mean profile timestamp;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Latitude;
Abbreviation: latitude;
Unit: degrees_north;
Observation type: Glider profile trajectory;
Measured or calculated: Calculated;
Calculation method and parameters: m_gps_lat (measured latitude) converted to decimal degrees and interpolated;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Longitude;
Abbreviation: longitude;
Unit: degrees_east;
Observation type: Glider profile trajectory;
Measured or calculated: Calculated;
Calculation method and parameters: m_gps_lon (measured longitude) converted to decimal degrees and interpolated;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Depth;
Abbreviation: depth;
Unit: m;
Observation type: Glider profile trajectory;
Measured or calculated: Calculated;
Calculation method and parameters: Calculated from pressure and latitude using gsw.z_from_p;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Sea-Bird GPCTD Pumped Conductivity, Temperature, Depth (CTD) Sensor. Serial Number 9916. Factory calibrated 2022-10-09</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Interpolated depth;
Abbreviation: depth_interpolated;
Unit: m;
Observation type: Glider profile trajectory;
Calculation method and parameters: Linear interpolated depth using pandas.DataFrame.interpolate;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Sea-Bird GPCTD Pumped Conductivity, Temperature, Depth (CTD) Sensor. Serial Number 9916. Factory calibrated 2022-10-09</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea water pressure;
Abbreviation: pressure;
Unit: dbar;
Observation type: Glider profile trajectory;
Measured or calculated: Measured;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Sea-Bird GPCTD Pumped Conductivity, Temperature, Depth (CTD) Sensor. Serial Number 9916. Factory calibrated 2022-10-09</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea water temperature;
Abbreviation: temperature;
Unit: degrees Celsius;
Observation type: Glider profile trajectory;
Measured or calculated: Measured;
Calculation method and parameters: Suspect/failed IOOS QC values, and values flagged by a CTD hysteresis test have been removed.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Sea-Bird GPCTD Pumped Conductivity, Temperature, Depth (CTD) Sensor. Serial Number 9916. Factory calibrated 2022-10-09</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea water conductivity;
Abbreviation: conductivity;
Unit: S m-1;
Observation type: Glider profile trajectory;
Measured or calculated: Measured;
Calculation method and parameters: Suspect/failed IOOS QC values, and values flagged by a CTD hysteresis test have been removed.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Sea-Bird GPCTD Pumped Conductivity, Temperature, Depth (CTD) Sensor. Serial Number 9916. Factory calibrated 2022-10-09</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea water density;
Abbreviation: density;
Unit: kg m-3;
Observation type: Glider profile trajectory;
Measured or calculated: Calculated;
Calculation method and parameters: Density calculated from temperature, practical salinity, pressure, latitude, and longitude using Gibbs gsw SA_from_SP, CT_from_t, and rho functions. Suspect/failed IOOS QC values, and values flagged by a CTD hysteresis test have been removed.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea water practical salinity;
Abbreviation: salinity;
Unit: 1;
Observation type: Glider profile trajectory;
Measured or calculated: CALCULATED;
Calculation method and parameters: Practical salinity calculated from conductivity, temperature, and pressure using the Gibbs gsw SP_from_C function. Suspect/failed IOOS QC values, and values flagged by a CTD hysteresis test have been removed.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Chlorophyll a;
Abbreviation: chlorophyll_a;
Unit: ug L-1;
Observation type: Glider profile trajectory;
Measured or calculated: Measured;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Sea-Bird ECO Triplet Puck FLBBCDSLC. Measures Chlorophyll a, beta700nm, CDOM. Serial number 7699. Factory calibrated 2022-08-03.</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Time-lag Adjusted Dissolved Oxygen;
Abbreviation: oxygen_concentration_shifted;
Unit: micromoles L-1;
Observation type: Glider profile trajectory;
Measured or calculated: CALCULATED;
Calculation method and parameters: Dissolved oxygen shifted by an optimal time shift calculated by glider segment in order to minimize separation between glider down and upcasts.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Aanderaa Oxygen Optode 4831. Serial number 242. Factory calibrated 2023-07-05.;
Method reference: Optimal time shifts applied in order to minimize separation between glider down and upcasts as described in Saba et al 2019 https://doi.org/10.3389/fmars.2019.00664 and Wright-Fairbanks et al 2020 https://doi.org/10.1029/2020JC016505</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Time-lag Adjusted Dissolved Oxygen Saturation;
Abbreviation: oxygen_saturation_shifted;
Unit: percent;
Observation type: Glider profile trajectory;
Measured or calculated: CALCULATED;
Calculation method and parameters: Dissolved oxygen saturation shifted by an optimal time shift calculated by glider segment in order to minimize separation between glider down and upcasts.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Aanderaa Oxygen Optode 4831. Serial number 242. Factory calibrated 2023-07-05.;
Method reference: Optimal time shifts applied in order to minimize separation between glider down and upcasts as described in Saba et al 2019 https://doi.org/10.3389/fmars.2019.00664 and Wright-Fairbanks et al 2020 https://doi.org/10.1029/2020JC016505</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Time-lag Adjusted Dissolved Oxygen;
Abbreviation: oxygen_concentration_shifted_mgL;
Unit: mg L-1;
Observation type: Glider profile trajectory;
Measured or calculated: CALCULATED;
Calculation method and parameters: Dissolved oxygen shifted by an optimal time shift calculated by glider segment in order to minimize separation between glider down and upcasts.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Aanderaa Oxygen Optode 4831. Serial number 242. Factory calibrated 2023-07-05.;
Method reference: Optimal time shifts applied in order to minimize separation between glider down and upcasts as described in Saba et al 2019 https://doi.org/10.3389/fmars.2019.00664 and Wright-Fairbanks et al 2020 https://doi.org/10.1029/2020JC016505</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pH reference voltage uncorrected;
Abbreviation: sbe41n_ph_ref_voltage;
Unit: volts;
Observation type: Glider profile trajectory;
Measured or calculated: Measured;
Calculation method and parameters: Raw measured pH reference voltage, no correction applied.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Sea-Bird Deep ISFET Ocean pH Sensor. Serial Number 12111. Factory calibrated 2022-10-21. Sensor calibration coefficents: "f1": 0.000009092056812525, "f2": 2.367514411577e-08, "f3": -1.289327778908e-10, "f4": 2.69055979149e-13, "f5": -3.184217390153e-16, "f6": 2.290504460079e-19, "f7": -9.895342051846e-23, "f8": 2.358877646314e-26, "f9": -2.383449353933e-30, "f10": 0, "f11": 0, "f12": 0, "k0": -1.308224882, "k2f0": -8.7852e-04, "k2f1": -4.4349e-08, "k2f2": 2.7615e-11, "k2f3": -6.2765e-15. Accuracy: Â±0.05 Precision Â±0.001;
Detailed sampling and analyzing information: Once the glider is deployed it completes vertical profiles to collect data throughout the water column. The pH sensor (sampling rate 1 Hz) is coupled to a CTD unit (sampling rate 0.5 Hz) on the glider to provide simultaneous measurements of measured reference voltage, salinity, pressure, and temperature. Standardization Technique Description: For the initial calibration, the pressure response function f(P), temperature response constants k2, and conditioning offset k0 are derived in a controlled laboratory. Calibrations for f(P) and k2 are performed in a pressure vessel with a working fluid of 0.01N Hydrochloric acid (HCl). pH sensors undergo oceanographic temperature ranges (5-35Â°C) and pressure ranges (0-3000 psi) for 1 week. For the k0 calibration, the sensor is conditioned to natural seawater for 3-5 days before k0 is calculated. For each subsequent maintenance calibration the sensor is cleaned, the sensor is re-conditioned to natural seawater and k0 is re-calculated. The pH sensor is factory calibrated by the manufacturer at least once per year.</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Time-lag Adjusted pH Reference Voltage;
Abbreviation: sbe41n_ph_ref_voltage_shifted;
Unit: volts;
Observation type: Glider profile trajectory;
Measured or calculated: Calculated;
Calculation method and parameters: Measured pH reference voltage shifted by an optimal time shift calculated by glider segment in order to minimize separation between glider down and upcasts.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Sea-Bird Deep ISFET Ocean pH Sensor. Serial Number 12111. Factory calibrated 2022-10-21. Sensor calibration coefficents: "f1": 0.000009092056812525, "f2": 2.367514411577e-08, "f3": -1.289327778908e-10, "f4": 2.69055979149e-13, "f5": -3.184217390153e-16, "f6": 2.290504460079e-19, "f7": -9.895342051846e-23, "f8": 2.358877646314e-26, "f9": -2.383449353933e-30, "f10": 0, "f11": 0, "f12": 0, "k0": -1.308224882, "k2f0": -8.7852e-04, "k2f1": -4.4349e-08, "k2f2": 2.7615e-11, "k2f3": -6.2765e-15. Accuracy: Â±0.05 Precision Â±0.001;
Detailed sampling and analyzing information: Once the glider is deployed it completes vertical profiles to collect data throughout the water column. The pH sensor (sampling rate 1 Hz) is coupled to a CTD unit (sampling rate 0.5 Hz) on the glider to provide simultaneous measurements of measured reference voltage, salinity, pressure, and temperature. Standardization Technique Description: For the initial calibration, the pressure response function f(P), temperature response constants k2, and conditioning offset k0 are derived in a controlled laboratory. Calibrations for f(P) and k2 are performed in a pressure vessel with a working fluid of 0.01N Hydrochloric acid (HCl). pH sensors undergo oceanographic temperature ranges (5-35Â°C) and pressure ranges (0-3000 psi) for 1 week. For the k0 calibration, the sensor is conditioned to natural seawater for 3-5 days before k0 is calculated. For each subsequent maintenance calibration the sensor is cleaned, the sensor is re-conditioned to natural seawater and k0 is re-calculated. The pH sensor is factory calibrated by the manufacturer at least once per year.;
Method reference: Optimal time shifts applied in order to minimize separation between glider down and upcasts as described in Saba et al 2019 https://doi.org/10.3389/fmars.2019.00664 and Wright-Fairbanks et al 2020 https://doi.org/10.1029/2020JC016505</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Time-lag Adjusted pH;
Abbreviation: pH;
Unit: 1;
Observation type: Glider profile trajectory;
Measured or calculated: CALCULATED;
Calculation method and parameters: Calculated from sensor calibration coefficents, interpolated pressure, interpolated salinity, interpolated temperature, and measured reference voltage shifted by an optimal time shift calculated by glider segment in order to minimize separation between glider down and upcasts. CTD variables are adjusted for thermal lag.;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Analyzing instrument: Sea-Bird Deep ISFET Ocean pH Sensor. Serial Number 12111. Factory calibrated 2022-10-21. Sensor calibration coefficents: "f1": 0.000009092056812525, "f2": 2.367514411577e-08, "f3": -1.289327778908e-10, "f4": 2.69055979149e-13, "f5": -3.184217390153e-16, "f6": 2.290504460079e-19, "f7": -9.895342051846e-23, "f8": 2.358877646314e-26, "f9": -2.383449353933e-30, "f10": 0, "f11": 0, "f12": 0, "k0": -1.308224882, "k2f0": -8.7852e-04, "k2f1": -4.4349e-08, "k2f2": 2.7615e-11, "k2f3": -6.2765e-15. Accuracy: Â±0.05 Precision Â±0.001;
Detailed sampling and analyzing information: Once the glider is deployed it completes vertical profiles to collect data throughout the water column. The pH sensor (sampling rate 1 Hz) is coupled to a CTD unit (sampling rate 0.5 Hz) on the glider to provide simultaneous measurements of measured reference voltage, salinity, pressure, and temperature. Standardization Technique Description: For the initial calibration, the pressure response function f(P), temperature response constants k2, and conditioning offset k0 are derived in a controlled laboratory. Calibrations for f(P) and k2 are performed in a pressure vessel with a working fluid of 0.01N Hydrochloric acid (HCl). pH sensors undergo oceanographic temperature ranges (5-35Â°C) and pressure ranges (0-3000 psi) for 1 week. For the k0 calibration, the sensor is conditioned to natural seawater for 3-5 days before k0 is calculated. For each subsequent maintenance calibration the sensor is cleaned, the sensor is re-conditioned to natural seawater and k0 is re-calculated. The pH sensor is factory calibrated by the manufacturer at least once per year.;
Uncertainty: Â±0.05;
Method reference: pH calculations were performed in Python as described in Saba et al 2019 https://doi.org/10.3389/fmars.2019.00664. Optimal time shifts applied in order to minimize separation between glider down and upcasts as described in Saba et al 2019 https://doi.org/10.3389/fmars.2019.00664 and Wright-Fairbanks et al 2020 https://doi.org/10.1029/2020JC016505</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Total alkalinity;
Abbreviation: total_alkalinity;
Unit: micromoles kg-1;
Observation type: Glider profile trajectory;
Measured or calculated: Calculated;
Calculation method and parameters: Estimated from salinity using a linear relationship (TA = m * salinity + b) with the following seasonal coefficients: ({'DJF': {'m': 48.71, 'b': 601.75}, 'MAM': {'m': 42.37, 'b': 817.59}, 'JJA': {'m': 50.75, 'b': 541.81}, 'SON': {'m': 46.42, 'b': 687.99}}) determined from in-situ water sampling data taken during glider deployments and recoveries in addition to ship-based water samples in the Mid-Atlantic Bight region as described in Wright-Fairbanks et al 2020 https://doi.org/10.1029/2020JC016505;
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Detailed sampling and analyzing information: Once the glider is deployed it completes vertical profiles to collect data throughout the water column. The pH sensor (sampling rate 1 Hz) is coupled to a CTD unit (sampling rate 0.5 Hz) on the glider to provide simultaneous measurements of measured reference voltage, salinity, pressure, and temperature. Total Alkalinity is estimated from salinity via the method described in Calculation Method and Parameters.;
Method reference: Wright-Fairbanks et al 2020 https://doi.org/10.1029/2020JC016505</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Aragonite saturation state;
Abbreviation: aragonite_saturation_state;
Unit: 1;
Observation type: Glider profile trajectory;
Measured or calculated: CALCULATED;
Calculation method and parameters: Calculated using PyCO2SYS (Humphreys et al. (2020) doi:10.5281/zenodo.3744275, Lewis and Wallace (1998)) with inputs of pH on the total scale, total alkalinity, in situ salinity, temperature, and pressure, K1 and K2 dissociation constants defined by Merbach and refit by Dickson and Millero, KSO4 dissociation constant of Dickson, KHF dissociation constant of Perez and Fraga, and borate-to-salinity ratio of Uppstrom (1979);
Sampling instrument: Teledyne Webb Research Slocum G3S glider ru34;
Detailed sampling and analyzing information: Once the glider is deployed it completes vertical profiles to collect data throughout the water column. The pH sensor (sampling rate 1 Hz) is coupled to a CTD unit (sampling rate 0.5 Hz) on the glider to provide simultaneous measurements of measured reference voltage, salinity, pressure, and temperature. Aragonite saturation state is estimated via the method described in Calculation Method and Parameters.</gco:CharacterString>
              </gmd:description>
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    </gmd:DQ_DataQuality>
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  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
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          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_beb7">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>conductivity sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>conductivity sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>OMEGA non-contact conductivity sensor CDCN-108 or Honeywell DirectLine DL423 Sensor Module, for example

Water conductivity sensors are used to measure how well a solution conducts an electrical current.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bee7">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>CTD</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>CTD</gco:CharacterString>
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            <gco:CharacterString>Conductivity-Temperature-Depth probe</gco:CharacterString>
          </gmi:description>
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      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bef4">
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                <gco:CharacterString>oxygen sensor</gco:CharacterString>
              </gmd:code>
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          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>oxygen sensor</gco:CharacterString>
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            <gco:CharacterString>Any instrument that measures oxygen content in a compound.</gco:CharacterString>
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        </gmi:MI_Instrument>
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      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bedd">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>pH sensor</gco:CharacterString>
              </gmd:code>
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          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>pH sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>generic meter used to measure pH

Any of a class of instruments used to quantify pH in a water or other type of sample.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
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      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be41">
          <gmi:identifier>
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          <gmi:type>
            <gco:CharacterString>temperature sensor</gco:CharacterString>
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          <gmi:description>
            <gco:CharacterString>A sensor used to measure temperature.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>